PENGUKURAN KADAR FLUORIDA, NITRAT, DAN NITRIT DALAM AIR SUMUR MENGGUNAKAN METODE SPEKTROFOTOMETRI UV-VIS

Khoirul Ngibad

Abstract


Fluoride is beneficial to human health but its excess or lack of water is harmful to humans as well as the environment and can cause fluorosis. On the other hand, the intake of high concentrations of nitrates and nitrites can cause methemoglobinemia. This study aims to analyze fluoride, nitrate, and nitrite levels in well water around Taman District, Sidoarjo Regency. The method used in this study was UV-Vis spectrophotometry at a wavelength of 570 nm for the measurement of fluoride levels and a wavelength of 543 nm for the measurement of nitrate and nitrite cadaver. The results showed that the well water around the Taman District of Sidoarjo Regency had fluoride, nitrate, and nitrite levels in the sample of 0.23 each; 0,73; and 0.019 mg/L (well water A) and 0.18; 0,8; and 0.042 mg/L (well water B). The fluoride, nitrate, and nitrite levels still meet the quality standard (maximum level) of chemical parameters in the environmental health quality standard for water media for sanitary hygiene purposes.

Keywords


well water; fluoride; nitrate; nitrite; UV-Vis spectrophotometry

Full Text:

PDF

References


Amanati, L. (2016). Uji Nitrit Pada Produk Air Minum Dalam Kemasan (Amdk) Yang Beredar Di Pasaran. Jurnal Teknologi Proses Dan Inovasi Industri, 1(2). https://doi.org/10.36048/jtpii.v1i2.1916

Arlina, A. I. C. U. C. U. K., Upriatna, A. D. I. M. U. S., & Malia, D. A. N. V. I. N. A. A. (2022). Analisis Kadar Nitrit ( NO 2 – N ) pada Sampel Air Permukaan dan Air Tanah di Wilayah Kabupaten Cilacap Menggunakan Metode Spektrofotometer Uv-Vis. Gunung Djati Conference Series, Volume 7 (2022), 7(2), 1–7. Prosiding Seminar Nasional Kimia 2021

Azhdarpoor, A., Radfard, M., Pakdel, M., Abbasnia, A., Badeenezhad, A., Mohammadi, A. A., & Yousefi, M. (2019). Assessing fluoride and nitrate contaminants in drinking water resources and their health risk assessment in a semiarid region of southwest Iran. Desalination and Water Treatment, 149, 43–51.

Aziz, F., Din, I., Khan, F., Manan, P., Sher, A., & Hakim, S. (2023). Treatment of fluoride contaminated water by using mango (Mangifera indica) leaves powder as an adsorbent. Current Research in Green and Sustainable Chemistry, 100359. https://doi.org/10.1016/j.crgsc.2023.100359

Badeenezhad, A., Radfard, M., Abbasi, F., Jurado, A., Bozorginia, M., Jalili, M., & Soleimani, H. (2021). Effect of land use changes on non-carcinogenic health risks due to nitrate exposure to drinking groundwater. Environmental Science and Pollution Research, 28, 41937–41947.

Barrett, J. H., Parslow, R. C., McKinney, P. A., Law, G. R., & Forman, D. (1998). Nitrate in drinking water and the incidence of gastric, esophageal, and brain cancer in Yorkshire, England. Cancer Causes & Control, 9, 153–159.

Blaisdell, J., Turyk, M. E., Almberg, K. S., Jones, R. M., & Stayner, L. T. (2019). Prenatal exposure to nitrate in drinking water and the risk of congenital anomalies. Environmental Research, 176, 108553.

BSN. (2001). SNI 6989.79:2011 tentang Air dan air limbah – Bagian 79: Cara uji nitrat (NO3-N) dengan spektrofotometer UV-visibel secara reduksi kadmium.

BSN. (2004). SNI 06-6989.9-2004 tentang Air dan air limbah – Bagian 9: Cara uji nitrit (NO2_N) secara spektrofotometri.

BSN. (2005). SNI 06-6989.29-2005 tentang Air dan air limbah – Bagian 29 : Cara uji fluorida (F- ) secara spektrofotometri dengan SPADNS.

Emilia, I. (2019). Analisa kandungan Nitrat dan Nitrit Dalam Air Minum Isi Ulang menggunakan Metode Spektrofotometri UV-Vis. Indobiosains, 1(1).

Ghosh, A., Mukherjee, K., Ghosh, S. K., & Saha, B. (2013). Sources and toxicity of fluoride in the environment. Research on Chemical Intermediates, 39, 2881–2915.

Ghosh, G., & Mukhopadhyay, D. K. (2019). Human health hazards due to arsenic and fluoride contamination in drinking water and food chain. Groundwater Development and Management: Issues and Challenges in South Asia, 351–369.

Giri, B. (2017). 13 - Determination of Nitrite Ions in Water Using Paper Analytical Device (B. B. T.-L. M. in M. Giri (ed.); pp. 83–88). Elsevier. https://doi.org/https://doi.org/10.1016/B978-0-12-813235-7.00013-1

Golaki, M., Azhdarpoor, A., Mohamadpour, A., Derakhshan, Z., & Conti, G. O. (2022). Health risk assessment and spatial distribution of nitrate, nitrite, fluoride, and coliform contaminants in drinking water resources of kazerun, Iran. Environmental Research, 203(June 2021), 111850. https://doi.org/10.1016/j.envres.2021.111850

Hanifah, H. N., Hendrayanti, H., & Mulyani, S. (2019). Analisis Kandungan Ion Fluorida Pada Sampel Air Minum Dalam Kemasan Secara Spektrofotometri Uv-Vis. Jurnal Sabdariffarma, 1(1), 28–33. https://doi.org/10.53675/jsfar.v1i1.18

Hendrawati, H., Prihadi, T. H., & Rohmah, N. N. (2008). Analisis kadar phosfat dan N-nitrogen (amonia, nitrat, nitrit) pada tambak air payau akibat rembesan lumpur lapindo di Sidoarjo, Jawa Timur. Jurnal Kimia VALENSI, 1(3).

Huan, H., Hu, L., Yang, Y., Jia, Y., Lian, X., Ma, X., Jiang, Y., & Xi, B. (2020). Groundwater nitrate pollution risk assessment of the groundwater source field based on the integrated numerical simulations in the unsaturated zone and saturated aquifer. Environment International, 137, 105532.

Jakszyn, P., & González, C. A. (2006). Nitrosamine and related food intake and gastric and oesophageal cancer risk: a systematic review of the epidemiological evidence. World Journal of Gastroenterology: WJG, 12(27), 4296.

Jannah, Z. N., Herawati, D., & Ngibad, K. (2021). REVIEW: Analisis Konsentrasi Ion Sulfat dalam Air Menggunakan Spektrofotometri. Jurnal Pijar Mipa, 16(2), 203–206. https://doi.org/10.29303/jpm.v16i2.1907

Juliasih, N. L. G. R., Hidayat, D., Ersa, M. P., & Rinawati. (2017). Penentuan Kadar Nitrit dan Nitrat pada Perairan Teluk Lampung sebagai Indikator Kualitas Lingkungan Perairan. Analit: Analytical and Environmental Chemistry, 2(02), 47–56.

Kaur, L., Rishi, M. S., & Siddiqui, A. U. (2020). Deterministic and probabilistic health risk assessment techniques to evaluate non-carcinogenic human health risk (NHHR) due to fluoride and nitrate in groundwater of Panipat, Haryana, India. Environmental Pollution, 259, 113711.

Ke, B., Chen, W., Ni, N., Cheng, Y., Dai, C., Dinh, H., & Wang, B. (2013). A fluorescent probe for rapid aqueous fluoride detection and cell imaging. Chemical Communications, 49(25), 2494–2496.

Kementerian Kesehatan RI. (2017). PERATURAN MENTERI KESEHATAN REPUBLIK INDONESIA NOMOR 32 TAHUN 2017 TENTANG Standar Baku Mutu Kesehatan Lingkungan dan Persyaratan Kesehatan Air Untuk Keperluan Higiene Sanitasi, Kolam Renang, Solus Per Aqua, dan Pemandian Umum.

Khan, M. A., Ahn, Y.-T., Kumar, M., Lee, W., Min, B., Kim, G., Cho, D.-W., Park, W. B., & Jeon, B.-H. (2011). Adsorption studies for the removal of nitrate using modified lignite granular activated carbon. Separation Science and Technology, 46(16), 2575–2584.

Li, K., Liu, H., Li, S., Li, Q., Li, S., & Wang, Q. (2023). The determinants of effective defluorination by the LiAl-LDHs. Journal of Environmental Sciences, 126, 153–162.

Loganathan, P., Vigneswaran, S., & Kandasamy, J. (2013). Enhanced removal of nitrate from water using surface modification of adsorbents–a review. Journal of Environmental Management, 131, 363–374.

Maulina Najib, C. A., & Nuzlia, C. (2020). Uji Kadar Flourida Pada Air Minum Dalam Kemasan (Amdk) Dan Air Sumur Secara Spektrofotometri Uv-Vis. Amina, 1(2), 84–90. https://doi.org/10.22373/amina.v1i2.43

Mohammadpour, A., Gharehchahi, E., Badeenezhad, A., Parseh, I., Khaksefidi, R., Golaki, M., Dehbandi, R., Azhdarpoor, A., Derakhshan, Z., & Rodriguez-Chueca, J. (2022). Nitrate in groundwater resources of Hormozgan province, southern Iran: concentration estimation, distribution and probabilistic health risk assessment using Monte Carlo simulation. Water, 14(4), 564.

Nadhila, H., & Nuzlia, C. (2021). Analisis Kadar Nitrit Pada Air Bersih Dengan Metode Spektrofotometri Uv-Vis. Amina, 1(3), 132–138. https://doi.org/10.22373/amina.v1i3.492

Najib, C. A. M., & Nuzlia, C. (2019). UJI KADAR FLOURIDA PADA AIR MINUM DALAM KEMASAN (AMDK) DAN AIR SUMUR SECARA SPEKTROFOTOMETRI UV-VIS. AMINA, 1(2), 84–90.

Ngibad, K. (2019). Penentuan Konsentrasi Ammoniumdalam Air Sungai Pelayaran Ngelom. Journal of Medical Laboratory Science Technology, 2(1), 37–42. https://doi.org/10.21070/medicra.v2i1.2071

Ngibad, K., & Herawati, D. (2019). ANALISIS KADAR KLORIDA DALAM AIR SUMUR DAN PDAM DI DESA NGELOM SIDOARJO. JKPK (JURNAL KIMIA DAN PENDIDIKAN KIMIA, 4(1), 1–6.

Nuradi, N., & Sam, T. W. (2019). Analisis Kadar Nitrit (No2) Pada Air Sumur Bor Di Daerah Persawahan Desa To’E Kecamatan Tiroang Kabupaten Pinrang. Jurnal Media Analis Kesehatan, 10(1), 44. https://doi.org/10.32382/mak.v10i1.1007

Nurhidayatullah, Sholehah, H., Susane, H., & khalidi, F. (2020). Jurnal Sanitasi dan Lingkungan PEMERIKSAAN KADAR NITRIT (NO2-) PADA AIR SUMUR GALI DI DESA JEMPONG KOTA MATARAM DENGAN METODE SPEKTROFOTOMETRI UV-VIS EXAMINATION OF NITRIT LEVELS (NO2-) IN GULL WELL WATER IN JEMPONG VILLAGE, MATARAM CITY USING UV-VIS SPEK. Jurnal Sanitasi Dan Lingkungan , 1(2). https://e-journal.sttl-mataram.ac.id

Prabowo, R. (2001). Kadar Nitrit Pada Sumber Air Sumur di kelurahan Meteseh, Kec. Tembalang, Kota Semarang. Cendikia Eksakta, 55(1), 55–61.

Prabowo, R., & Dewi, N. K. (2017). Kandungan Nitrit Pada Air Sumur Gali Di Kelurahan Meteseh, Kecamatan. Tembalang Kota Semarang. Bioma : Jurnal Ilmiah Biologi, 5(1), 1–15. https://doi.org/10.26877/bioma.v5i1.1490

Putri, A. N. N., & Abdullah, S. (2019). Studi Kandungan Fluorida Pada Air Penampungan Air Hujan. Buletin Keslingmas, 38(3), 268–276. https://doi.org/10.31983/keslingmas.v38i3.5395

Rezaei, H., Jafari, A., Kamarehie, B., Fakhri, Y., Ghaderpoury, A., Karami, M. A., Ghaderpoori, M., Shams, M., Bidarpoor, F., & Salimi, M. (2019). Health-risk assessment related to the fluoride, nitrate, and nitrite in the drinking water in the Sanandaj, Kurdistan County, Iran. Human and Ecological Risk Assessment, 25(5), 1242–1250. https://doi.org/10.1080/10807039.2018.1463510

Rinda, R., Salakory, M., & Leuwol, F. S. (2022). Analisis Kualitas Dan Kuantitas Air Sumur Gali Di Dusun Pulau Osi Kecamatan Seram Barat Kabupaten Seram Bagian Barat. Jurnal Pendidikan Geografi Unpatti, 1(1), 47–59.

Schoeman, J. J., & Steyn, A. (2003). Nitrate removal with reverse osmosis in a rural area in South Africa. Desalination, 155(1), 15–26.

Senewirathna, D., Thuraisingam, S., Prabagar, S., & Prabagar, J. (2022). Fluoride removal in drinking water using activated carbon prepared from palmyrah (Borassus flabellifer) nut shells. Current Research in Green and Sustainable Chemistry, 5, 100304.

Serio, F., Miglietta, P. P., Lamastra, L., Ficocelli, S., Intini, F., De Leo, F., & De Donno, A. (2018). Groundwater nitrate contamination and agricultural land use: A grey water footprint perspective in Southern Apulia Region (Italy). Science of the Total Environment, 645, 1425–1431.

Shen, Y., Chen, N., Feng, Z., Feng, C., & Deng, Y. (2022). Treatment of nitrate containing wastewater by adsorption process using polypyrrole-modified plastic-carbon: Characteristic and mechanism. Chemosphere, 297, 134107.

Shuval, H. I., & Gruener, N. (2013). Infant methemoglobinemia and other health effects of nitrates in drinking water. Proceedings of the Conference on Nitrogen as a Water Pollutant, 183–193.

Tiwari, A. K., & Singh, A. K. (2014). Hydrogeochemical investigation and groundwater quality assessment of Pratapgarh district, Uttar Pradesh. J Geol Soc India, 83(3), 329–343.

Triarini, L. J., Amalia, L. R., Damayanti, N. K., & Ngibad, K. (2021). Analisis Kadar COD Pada Air Sumur Desa Ngelom Sepanjang Menggunakan Metode Titrimetri. Universitas Maarif Hasyim Latif, 7, 914–918.

Tsikas, D. (2007). Analysis of nitrite and nitrate in biological fluids by assays based on the Griess reaction: appraisal of the Griess reaction in the L-arginine/nitric oxide area of research. Journal of Chromatography B, 851(1–2), 51–70.

Ward, M. H., Jones, R. R., Brender, J. D., De Kok, T. M., Weyer, P. J., Nolan, B. T., Villanueva, C. M., & Van Breda, S. G. (2018). Drinking water nitrate and human health: an updated review. International Journal of Environmental Research and Public Health, 15(7), 1557.

Zhang, L., Zhao, L., Zeng, Q., Fu, G., Feng, B., Lin, X., Liu, Z., Wang, Y., & Hou, C. (2020). Spatial distribution of fluoride in drinking water and health risk assessment of children in typical fluorosis areas in north China. Chemosphere, 239, 124811.

Zuo, H., Chen, L., Kong, M., Qiu, L., Lü, P., Wu, P., Yang, Y., & Chen, K. (2018). Toxic effects of fluoride on organisms. Life Sciences, 198, 18–24.




DOI: https://doi.org/10.30743/cheds.v7i1.6791

Refbacks

  • There are currently no refbacks.


Copyright (c) 2023 Khoirul Ngibad

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

 

CHEDS: Journal of Chemistry, Education, and Science

Program Studi Pendidikan Kimia, FKIP - Universitas Islam Sumatera Utara
Kampus Induk UISU Jl. Sisingamangaraja XII Teladan, Medan 
Email: pend.kimia@fkip.uisu.ac.id | cheds@fkip.uisu.ac.id

Creative Commons License